PbO2 (s) + 2 KBr (aq) + 2 H2SO4 (aq) → Br2 (aq) + PbSO4 (s) + K2SO4 (aq) + 2 H2O (l)

This is an oxidation-reduction (redox) reaction:

2 Br-I - 2 e- → 2 Br0 (oxidation)

PbIV + 2 e- → PbII (reduction)

KBr is a reducing agent, PbO2 is an oxidizing agent.

Reactants:

  • PbO2 – Lead(IV) oxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04
    • Other names: Lead dioxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Plumbic oxide source: wikipedia, accessed: 2019-09-27, Plattnerite source: wikipedia, accessed: 2019-09-27, Lead peroxide source: ICSC, accessed: 2019-09-04
    • Appearance: Dark-brown, black powder source: wikipedia, accessed: 2019-09-27; Brown crystals or powder source: ICSC, accessed: 2019-09-04
  • KBr
    • Names: Potassium bromide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, KBr source: wikidata, accessed: 2019-09-02, Kaliumbromid source: wikidata, accessed: 2019-09-02
    • Appearance: White solid source: wikipedia, accessed: 2019-09-27
  • H2SO4 – Sulfuric acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-07source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Oil of vitriol source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Sulfuric acid, concentrated (> 51% and < 100%) source: ICSC, accessed: 2019-09-04, H2SO4 source: wikidata, accessed: 2019-09-07
    • Appearance: Clear, colorless liquid source: wikipedia, accessed: 2019-09-27; Odourless colourless oily hygroscopic liquid source: ICSC, accessed: 2019-09-04; Colorless to dark-brown, oily, odorless liquid. [Note: Pure compound is a solid below 51°F. Often used in an aqueous solution.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • Br2
    • Names: Bromine source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Molecular bromine source: NIOSH NPG, accessed: 2019-09-02
    • Appearance: Fuming red-to-brown liquid with pungent odour source: ICSC, accessed: 2019-09-04; Dark reddish-brown, fuming liquid with suffocating, irritating fumes. source: NIOSH NPG, accessed: 2019-09-02
  • PbSO4 – Lead(II) sulfate source: wikipedia, accessed: 2019-09-27
    • Other names: Anglesite source: wikipedia, accessed: 2019-09-27, Fast white source: wikipedia, accessed: 2019-09-27, Milk white source: wikipedia, accessed: 2019-09-27
    • Appearance: White solid source: wikipedia, accessed: 2019-09-27
  • K2SO4
    • Names: Potassium sulfate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Potassium sulphate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Dipotassium sulfate source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04
    • Appearance: White solid source: wikipedia, accessed: 2019-09-27; Colourless-to-white crystals source: ICSC, accessed: 2019-09-04
  • H2O – Water, oxidane source: wikipedia, accessed: 2019-09-27
    • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27