6 NaBr + Na2Cr2O7 + 14 HCl → 3 Br2 + 2 CrCl3 + 8 NaCl + 7 H2O

This is an oxidation-reduction (redox) reaction:

6 Br-I - 6 e- → 6 Br0 (oxidation)

2 CrVI + 6 e- → 2 CrIII (reduction)

NaBr is a reducing agent, Na2Cr2O7 is an oxidizing agent.

Reactants:

  • NaBr – Sodium bromide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Other names: Bromide salt of sodium source: wikidata, accessed: 2019-09-02, Trisodium tribromide source: wikidata, accessed: 2019-09-02, NaBr source: wikidata, accessed: 2019-09-02
    • Appearance: White powder, hygroscopic source: wikipedia, accessed: 2019-09-27
  • Na2Cr2O7 – Sodium dichromate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Other names: Chromic acid disodium salt source: wikipedia, accessed: 2019-09-27, Sodium dichromate (anhydrous) source: ICSC, accessed: 2019-09-04, Disodium salt source: wikidata, accessed: 2019-09-02
    • Appearance: Bright orange source: wikipedia, accessed: 2019-09-27; Red-to-orange hygroscopic crystals source: ICSC, accessed: 2019-09-04
  • HCl – Chlorane source: wikipedia, accessed: 2019-09-27, Hydrogen chloride source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Hydrochloric acid source: wikipedia, accessed: 2019-09-27source: NIOSH NPG, accessed: 2019-09-02, M source: wikipedia, accessed: 2019-09-27, Uriatic acid source: wikipedia, accessed: 2019-09-27
    • Appearance: Colorless, transparent liquid, fumes in air if concentrated source: wikipedia, accessed: 2019-09-27; Colorless gas source: wikipedia, accessed: 2019-09-27; Colourless compressed liquefied gas with pungent odour source: ICSC, accessed: 2019-09-04; Colorless to slightly yellow gas with a pungent, irritating odor. [Note: Shipped as a liquefied compressed gas.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • Br2
    • Names: Bromine source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Molecular bromine source: NIOSH NPG, accessed: 2019-09-02
    • Appearance: Fuming red-to-brown liquid with pungent odour source: ICSC, accessed: 2019-09-04; Dark reddish-brown, fuming liquid with suffocating, irritating fumes. source: NIOSH NPG, accessed: 2019-09-02
  • CrCl3 – Chromium(III) chloride source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Chromium trichloride source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04
    • Other names: Chromic chloride source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Chromium(iii) chloride (anhydrous) source: ICSC, accessed: 2019-09-04, Chromium(3+) trichloride source: wikidata, accessed: 2019-09-02
    • Appearance: Purple (anhydrous), dark green (hexahydrate) source: wikipedia, accessed: 2019-09-27; Violet crystals source: ICSC, accessed: 2019-09-04
  • NaCl – Sodium chloride source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Other names: {{unbulleted list source: wikipedia, accessed: 2019-09-27, Salt source: wikidata, accessed: 2019-09-02, Table salt source: wikidata, accessed: 2019-09-02
    • Appearance: Colorless cubic crystals source: wikipedia, accessed: 2019-09-27
  • H2O – Water, oxidane source: wikipedia, accessed: 2019-09-27
    • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27