4 Na2SO3 (aq) → Na2S (aq) + 3 Na2SO4 (aq)

This is an oxidation-reduction (redox) reaction:

SIV + 6 e- → S-II (reduction)

3 SIV - 6 e- → 3 SVI (oxidation)

Na2SO3 is both an oxidizing and a reducing agent (disproportionation (dismutation)).

Reactants:

  • Na2SO3 – Sodium sulfite source: wikipedia, accessed: 2019-09-28source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04
    • Other names: Sodium sulphite source: wikipedia, accessed: 2019-09-28source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Hypo clear (photography) source: wikipedia, accessed: 2019-09-28, E221 source: wikipedia, accessed: 2019-09-28
    • Appearance: White solid source: wikipedia, accessed: 2019-09-28; White crystals or powder source: ICSC, accessed: 2019-09-04

Products:

  • Na2S
    • Names: Sodium sulfide source: wikipedia, accessed: 2019-09-28source: wikidata, accessed: 2019-09-02, Disodium sulfide source: wikipedia, accessed: 2019-09-28source: wikidata, accessed: 2019-09-02, Sodium sulfide (anhydrous) source: ICSC, accessed: 2019-09-04
    • Appearance: Colorless, hygroscopic solid source: wikipedia, accessed: 2019-09-28; White-to-yellow hygroscopic crystals with characteristic odour source: ICSC, accessed: 2019-09-04
  • Na2SO4
    • Names: Sodium sulfate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Sodium sulphate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Sulfate of sodium source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid | hygroscopic source: wikipedia, accessed: 2019-09-27; White hygroscopic solid in various forms source: ICSC, accessed: 2019-09-04