2 MnO2 + 3 NaBiO3 + 6 HNO3 → 2 HMnO4 + 3 BiONO3 + 3 NaNO3 + 2 H2O

This is an oxidation-reduction (redox) reaction:

2 MnIV - 6 e- → 2 MnVII (oxidation)

3 BiV + 6 e- → 3 BiIII (reduction)

MnO2 is a reducing agent, NaBiO3 is an oxidizing agent.

Reactants:

  • MnO2 – Manganese oxide source: wikipedia, accessed: 2019-09-27, Manganese(IV) oxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Other names: Manganese dioxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Pyrolusite source: wikipedia, accessed: 2019-09-27, Hyperoxide of manganese source: wikipedia, accessed: 2019-09-27
    • Appearance: Brown-black solid source: wikipedia, accessed: 2019-09-27; Black-to-brown powder source: ICSC, accessed: 2019-09-04
  • NaBiO3
    • Names: Sodium bismuthate source: wikidata, accessed: 2019-09-02
  • HNO3 – Nitric acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Aqua fortis source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02, Spirit of niter source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Eau forte source: wikipedia, accessed: 2019-09-27
    • Appearance: Colorless, yellow or red fuming liquid source: wikipedia, accessed: 2019-09-27; Colourless-to-yellow liquid with pungent odour source: ICSC, accessed: 2019-09-04; Colorless, yellow, or red, fuming liquid with an acrid, suffocating odor. [Note: Often used in an aqueous solution. Fuming nitric acid is concentrated nitric acid that contains dissolved nitrogen dioxide.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • HMnO4
    • Names: Permanganic acid source: wikidata, accessed: 2019-09-02, Manganic(VII) acid source: wikidata, accessed: 2019-09-02, HMnO4 source: wikidata, accessed: 2019-09-02, [MnO3(OH)] source: wikidata, accessed: 2019-09-02
  • BiONO3
    • Names: Bismuth oxynitrate source: wikidata, accessed: 2019-09-02
  • NaNO3 – Sodium nitrate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04
    • Other names: Peru saltpeter source: wikipedia, accessed: 2019-09-27, Soda niter source: wikipedia, accessed: 2019-09-27, Cubic niter source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Appearance: White powder or colorless crystals source: wikipedia, accessed: 2019-09-27; Colourless hygroscopic crystals source: ICSC, accessed: 2019-09-04
  • H2O – Water, oxidane source: wikipedia, accessed: 2019-09-27
    • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27