8 KMnO4 + KI + 8 KOH → 8 K2MnO4 + KIO4 + 4 H2O

This is an oxidation-reduction (redox) reaction:

8 MnVII + 8 e- → 8 MnVI (reduction)

I-I - 8 e- → IVII (oxidation)

KMnO4 is an oxidizing agent, KI is a reducing agent.

Reactants:

  • KMnO4 – Potassium manganate(VII) source: wikipedia, accessed: 2019-09-27
    • Other names: Potassium permanganate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Chameleon mineral source: wikipedia, accessed: 2019-09-27, Condy's crystals source: wikipedia, accessed: 2019-09-27
    • Appearance: Purplish-bronze-gray needles | magenta–rose in solution source: wikipedia, accessed: 2019-09-27; Dark purple crystals source: ICSC, accessed: 2019-09-04
  • KI
    • Names: Potassium iodide source: wikidata, accessed: 2019-09-02, KI source: wikidata, accessed: 2019-09-02, Thyrosafe source: wikidata, accessed: 2019-09-02
  • KOH – Potassium hydroxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Caustic potash source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Lye source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Potash lye source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Appearance: White solid, deliquescent source: wikipedia, accessed: 2019-09-27; White hygroscopic solid in various forms source: ICSC, accessed: 2019-09-04; Odorless, white or slightly yellow lumps, rods, flakes, sticks, or pellets. [Note: May be used as an aqueous solution.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • K2MnO4 – Potassium manganate(VI) source: wikipedia, accessed: 2019-09-27
    • Other names: Potassium manganate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Appearance: Green crystals (darkening with time) source: wikipedia, accessed: 2019-09-27
  • KIO4 – Potassium periodate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Other names: Potassium metaperiodate source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline powder source: wikipedia, accessed: 2019-09-27
  • H2O – Water, oxidane source: wikipedia, accessed: 2019-09-27
    • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27